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Catalysis

Working Paper

[Co(TPP)]–Catalyzed Carbene Transfer from Acceptor–Acceptor Iodonium Ylides via N-enolate Carbene Radicals

Roel F.J. Epping, Mees M. Hoeksma, Eduard O. Bobylev, Simon Mathew, Bas de Bruin

Version 1 posted 15 June 2021

580

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Catalysis

Working Paper

Electro-mediated PhotoRedox Catalysis for Selective C(sp3)-O Cleavages of Phosphinates to Carbanions

Xianhai Tian, Tobias Karl, Sebastian Reiter, Shahboz Yakubov, Regina de Vivie-Riedle, Burkhard Koenig, Joshua Barham

Version 1 posted 11 June 2021

740

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Catalysis

Working Paper

N-Heterocyclic Carbene-Catalyzed Synthesis of Ynones via C–H Alkynylation of Aldehydes with Alkynyliodonium Salts

Adam A. Rajkiewicz, Natalia Wojciechowska, Marcin Kalek

Version 1 posted 11 October 2019

628

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Materials Science

Working Paper

Substituent Effects of Amines on Genipin Dye Formation – Insights into Dye Origins

Fiona Jeeva, Chris Caputo

Version 1 posted 19 January 2021

336

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Catalysis

Working Paper

Mechanism of the Iridium-Catalyzed Silylation of Aromatic C–H Bonds

Caleb Karmel, John Hartwig

Version 1 posted 26 March 2020

690

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Organic Chemistry

Working Paper

Mechanism of Iodine(III)-Promoted Oxidative Dearomatizing Hydroxylation of Phenols: Evidence for Radical-Chain Pathway

Karol Kraszewski, Ireneusz Tomczyk, Aneta Drabinska, Krzysztof Bienkowski, Renata Solarska, Marcin Kalek

Version 1 posted 10 April 2020

1,200

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Organometallic Chemistry

Working Paper

Mechanism of the Arene-Limited Nondirected C–H Activation of Arenes with Palladium

Philipp Wedi, Mirxan Farizyan, Klaus Bergander, Christian Mück-Lichtenfeld, Manuel van Gemmeren

Version 3 posted 15 April 2021

1,334

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Organic Chemistry

Working Paper

Catalytic Benzolactamization Through Isonitrile Insertion Enabled 1,4-Palladium Shift

Fulin Zhang, Ruihua Zhao, Lei Zhu, Yinghua Yu, Saihu Liao, Zhi-Xiang Wang, Xueliang Huang

Version 1 posted 26 May 2021

415

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Analytical Chemistry

Working Paper

Unraveling Hydrogen Atom Transfer Mechanisms with Voltammetry: Oxidative Formation and Reactivity of Cobalt Hydride

Dylan Boucher, Andrew Pendergast, Xiangyu Wu, Zachary Nguyen, Song Lin, Henry White, Shelley Minteer

Version 1 posted 05 April 2023

559

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2

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Organic Chemistry

Working Paper

Amine-Catalyzed Copper-Mediated C–H Sulfonylation of Benzaldehydes via a Transient Imine Directing Group

Joe Higham, James A Bull

Version 2 posted 22 February 2022

1,186

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14 results in Mechanistic studies in Keywords: Mechanistic studies

[Co(TPP)]–Catalyzed Carbene Transfer from Acceptor–Acceptor Iodonium Ylides via N-enolate Carbene Radicals

Electro-mediated PhotoRedox Catalysis for Selective C(sp3)-O Cleavages of Phosphinates to Carbanions

N-Heterocyclic Carbene-Catalyzed Synthesis of Ynones via C–H Alkynylation of Aldehydes with Alkynyliodonium Salts

Substituent Effects of Amines on Genipin Dye Formation – Insights into Dye Origins

Mechanism of the Iridium-Catalyzed Silylation of Aromatic C–H Bonds

Mechanism of Iodine(III)-Promoted Oxidative Dearomatizing Hydroxylation of Phenols: Evidence for Radical-Chain Pathway

Mechanism of the Arene-Limited Nondirected C–H Activation of Arenes with Palladium

Catalytic Benzolactamization Through Isonitrile Insertion Enabled 1,4-Palladium Shift

Unraveling Hydrogen Atom Transfer Mechanisms with Voltammetry: Oxidative Formation and Reactivity of Cobalt Hydride

Amine-Catalyzed Copper-Mediated C–H Sulfonylation of Benzaldehydes via a Transient Imine Directing Group

14 results in Keywords: Mechanistic studies