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Organometallic Chemistry

Working Paper

Catalyst Design in C–H Activation: A Case Study in the Use of Binding Free Energies to Rationalise Intramolecular Directing Group Selectivity in Iridium Catalysis

William Kerr, Gary J. Knox, Marc Reid, Tell Tuttle

Version 2 posted 21 January 2021

471

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Catalysis

Working Paper

Late-Stage β-C(sp3)–H Deuteration of Carboxylic Acids

Alexander Uttry, Sourjya Mal, Manuel van Gemmeren

Version 2 posted 11 May 2021

1,062

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Organic Chemistry

Working Paper

Hexafluorophosphate-Triggered Hydrogen Isotope Exchange (HIE) in Fluorinated Environments: A Platform for the Deuteration of Aromatic Compounds via Strong Bond Activation

Yang Ni, Jonathan Lebelt, Milena Barb, Florian Kreuter, Hannah Buttkus, Jiaye Jin, Martin Kretzschmar, Ralf Tonner-Zech, Knut Asmis, Tanja Gulder

Version 1 posted 16 September 2024

209

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Organometallic Chemistry

Working Paper

Are Rate and Selectivity Correlated in Iridium-Catalysed Hydrogen Isotope Exchange Reactions?

Daria Timofeeva, David Lindsay, William Kerr, David Nelson

Version 1 posted 21 April 2021

268

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Catalysis

Working Paper

Site-Selective and Late-Stage Deuteration of (Hetero)arenes with Supported Iridium Nanoparticles

Chengbo Yao, Christophe Copéret

Version 1 posted 03 September 2024

253

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Catalysis

Working Paper

Cp*Co-catalyzed directed hydrogen isotope exchange with substrate-dependent deuterium source

Sergio Barranco, Inbal Zaik, Jiayu Zhang, Anat Milo, Monica Perez-Temprano

Version 1 posted 20 July 2023

689

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Organic Chemistry

Working Paper

Electrochemical Hydrogen Isotope Exchange of Amines Controlled by Alternating Current Frequency

Nibedita Behera, Disni Gunasekera, Jyoti Mahajan, Joseph Frimpong, Zhenfei Liu, Long Luo

Version 1 posted 21 February 2023

401

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Catalysis

Working Paper

Undirected, Pd-catalysed deuteration of indoles with programmable regioselectivity

Liam Fitzgerald, Rachael McNulty, Andrew Greener, Miriam O'Duill

Version 1 posted 18 July 2022

759

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Organic Chemistry

Working Paper

Synthesis of 15N-Pyridines and Higher Mass Isotopologs via Zincke Imine Intermediates

Hillary M. H. Nguyen, David C. Thomas, Marie A. Hart, Kaila R. Steenback, Jeffrey N. Levy, Andrew McNally

Version 1 posted 02 November 2023

1,413

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Catalysis

Working Paper

Alkane Dehydrogenation and H/D Exchange by a Cationic Pincer-Ir(III) Hydride: A Novel Mechanism of C-H Addition and 𝛽-H Elimination Leads to Unprecedented Selectivity

Ashish Parihar, Thomas J. Emge, Faraj Hasanayn, Alan S. Goldman

Version 1 posted 29 October 2024

249

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10 results in hydrogen isotope exchange in Keywords: hydrogen isotope exchange

Catalyst Design in C–H Activation: A Case Study in the Use of Binding Free Energies to Rationalise Intramolecular Directing Group Selectivity in Iridium Catalysis

Late-Stage β-C(sp3)–H Deuteration of Carboxylic Acids

Hexafluorophosphate-Triggered Hydrogen Isotope Exchange (HIE) in Fluorinated Environments: A Platform for the Deuteration of Aromatic Compounds via Strong Bond Activation

Are Rate and Selectivity Correlated in Iridium-Catalysed Hydrogen Isotope Exchange Reactions?

Site-Selective and Late-Stage Deuteration of (Hetero)arenes with Supported Iridium Nanoparticles

Cp*Co-catalyzed directed hydrogen isotope exchange with substrate-dependent deuterium source

Electrochemical Hydrogen Isotope Exchange of Amines Controlled by Alternating Current Frequency

Undirected, Pd-catalysed deuteration of indoles with programmable regioselectivity

Synthesis of 15N-Pyridines and Higher Mass Isotopologs via Zincke Imine Intermediates

Alkane Dehydrogenation and H/D Exchange by a Cationic Pincer-Ir(III) Hydride: A Novel Mechanism of C-H Addition and 𝛽-H Elimination Leads to Unprecedented Selectivity

10 results in Keywords: hydrogen isotope exchange