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The Geometry of the Catalytic Active Site in [FeFe]-Hydrogenases is Determined by Hydrogen Bonding and Proton Transfer

Jifu Duan, Stefan Mebs, Moritz Senger, Konstantin Laun, Florian Wittkamp, Joachim Heberle, Thomas Happe, Eckhard Hofmann, Ulf-Peter Apfel, Martin Winkler, Michael Haumann, Sven T. Stripp

Version 1 posted 22 February 2019

579

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Catalysis

Working Paper

The Plug-Lock-Lid Mechanism as Prerequisite for Rapid in vitro Maturation of [FeFe]-Hydrogenases

Jan Jaenecke, Konstantin Bikbaev, Julia Bronold, Shanika Yadav, Ulf Apfel, James Birrell, Ingrid Span, Nicolas Plumeré, Martin Winkler

Version 1 posted 27 January 2025

149

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Inorganic Chemistry

Working Paper

Site-selective Protonation of the One-electron Reduced Cofactor in [FeFe]-Hydrogenase

Konstantin Laun, Iuliia Baranova, Jifu Duan, Leonie Kertess, Florian Wittkamp, Ulf-Peter Apfel, Thomas Happe, Moritz Senger, Sven T. Stripp

Version 3 posted 16 September 2020

1,186

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1

Citations

Physical Chemistry

Working Paper

Trapping an Oxidized and Protonated Intermediate of the [FeFe]-Hydrogenase Cofactor under Mildly Reducing Conditions

Moritz Senger, Jifu Duan, Mariia V. Pavliuk, Ulf-Peter Apfel, Michael Haumann, Sven Stripp

Version 1 posted 28 February 2022

333

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Biological and Medicinal Chemistry

Working Paper

How [FeFe]-Hydrogenase Facilitates Bidirectional Proton Transfer

Moritz Senger, Viktor Eichmann, Konstantin Laun, Jifu Duan, Florian Wittkamp, Günther Knör, Ulf-Peter Apfel, Thomas Happe, Martin Winkler, Joachim Heberle, Sven T. Stripp

Version 2 posted 26 June 2019

504

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Catalysis

Working Paper

Oxygen Sensitivity of [FeFe]-Hydrogenase: A Comparative Study of Active Site Mimics Inside vs Outside the Enzyme

Shanika Yadav, Rieke Haas, Esma Birsen Boydas, Michael Römelt, Thomas Happe, Ulf-Peter Apfel, Sven Stripp

Version 2 posted 04 October 2023

769

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1

Citations

Inorganic Chemistry

Working Paper

Ligand Non-Innocence and Proton Channel Promote Cobalt-Catalyzed Electrochemical CO2 Reduction with Predominant CO Selectivity

Ayan Bera, Sarah Bimmermann, Dibya Jyoti Barman, Leon Gerndt, Thomas Lohmiller, Kaltum Abdiaziz, Maylis Orio, Alexander Schnegg, Kara L. Bren, Dennis G. H. Hetterscheid, Michael Römelt, Ulf-Peter Apfel, Kallol Ray

Version 1 posted 17 September 2024

350

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7 results in Ulf Apfel in Authors: Ulf Apfel

The Geometry of the Catalytic Active Site in [FeFe]-Hydrogenases is Determined by Hydrogen Bonding and Proton Transfer

The Plug-Lock-Lid Mechanism as Prerequisite for Rapid in vitro Maturation of [FeFe]-Hydrogenases

Site-selective Protonation of the One-electron Reduced Cofactor in [FeFe]-Hydrogenase

Trapping an Oxidized and Protonated Intermediate of the [FeFe]-Hydrogenase Cofactor under Mildly Reducing Conditions

How [FeFe]-Hydrogenase Facilitates Bidirectional Proton Transfer

Oxygen Sensitivity of [FeFe]-Hydrogenase: A Comparative Study of Active Site Mimics Inside vs Outside the Enzyme

Ligand Non-Innocence and Proton Channel Promote Cobalt-Catalyzed Electrochemical CO2 Reduction with Predominant CO Selectivity

7 results in Authors: Ulf Apfel