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Organic Chemistry

Working Paper

An Asymmetric Aromatic Finkelstein Reaction: A Platform for Remote Diarylmethane Desymmetrization

Tobias Morack, Tyler Myers, Lucas Karas, Melissa Hardy, Brandon Mercado, Matthew Sigman, Scott Miller

Version 1 posted 11 August 2023

611

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Organic Chemistry

Working Paper

SMARTpy: A Python Package for the Generation of Cavity-Specific Steric Molecular Descriptors and Applications to Diverse Systems

Beck Miller, Ryan Cammarota, Matthew Sigman

Version 1 posted 24 September 2024

311

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Organic Chemistry

Working Paper

Understanding Catalytic Enantioselective C-H Bond Oxidation at Nonactivated Methylenes Through Predictive Statistical Modeling Analysis

Arnau Call, Andrea Palone, Jordan P. Liles, Natalie P. Romer, Jacquelyne A. Read, Josep Maria Luis, Matthew S. Sigman, Massimo Bietti, Miquel Costas

Version 1 posted 17 September 2024

296

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Organic Chemistry

Working Paper

Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation

Brittany Haas, Ngiap-Kie Lim, Janis Jermaks, Eden Gaster, Melody Guo, Thomas Malig, Jacob Werth, Haiming Zhang, F. Dean Toste, Francis Gosselin, Scott Miller, Matthew Sigman

Version 1 posted 09 January 2024

1,179

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Organic Chemistry

Working Paper

Development of a Simple Thioetherification of Heteroarene Electrophiles with Broad Scope via a Proton Transfer Dual Ioni-zation Mechanism

Christian Zwick, Jeremy Henle, Shashank Shekhar, Cassie Yang, Yong Zhou, Amanda Wall, Rodger Henry, Matthew Sigman, Maike Eckhoff, Jessica Hoskins, Rafal Swiatowiec, Anna Bay

Version 2 posted 19 December 2024

1,043

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Organic Chemistry

Working Paper

Predicting Success in Cu-Catalyzed C–N Coupling Reactions using Data Science

Mohammad Samha, Lucas Karas, David Vogt, Emmanuel Odogwu, Jennifer Elward, Jennifer Crawford, Janelle Steves, Matthew Sigman

Version 1 posted 25 October 2023

1,130

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Organic Chemistry

Working Paper

14N to 15N Isotopic Exchange of Nitrogen Heteroaromatics through Skeletal Editing

G. Logan Bartholomew, Samantha L. Kraus, Lucas J. Karas, Filippo Carpaneto, Raffeal Bennett, Matthew S. Sigman, Charles S. Yeung, Richmond Sarpong

Version 1 posted 05 October 2023

2,929

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Catalysis

Working Paper

N-Ammonium Ylide Mediators for Selective Electrochemical C–H Oxidation

Masato Saito, Yu Kawamata, Michael Meanwell, Rafael Navratil, Debora Chiodi, Ethan Carlson, Pengfei Hu, Longrui Chen, Sagar Udyavara, Cian Kingston, Mayank Tanwar, Sameer Tyagi, Bruce Mckillican, Moses Gichinga, Michael A. Schmidt, Martin Eastgate, Max Lamberto, Chi He, Tianhua Tang, Christian A. Malapit, Matthew S. Sigman, Shelley D. Minteer, Matthew Neurock, Phil Baran

Version 1 posted 19 February 2021

1,934

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Catalysis

Working Paper

Data-driven multi-objective optimization tactics for catalytic asymmetric reactions

Jordan Dotson, Lucy van Dijk, Jacob Timmerman, Samantha Grosslight, Richard Walroth, Kurt Püntener, Francis Gosselin, Kyle Mack, Matthew Sigman

Version 1 posted 24 June 2022

2,114

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Organic Chemistry

Working Paper

Generality-Oriented Optimization of Enantioselective Aminoxyl Radical Catalysis

Jonas Rein, Soren Rozema, Olivia Langner, Samson Zacate, Melissa Hardy, Juno Siu, Brandon Mercado, Matthew Sigman, Scott Miller, Song Lin

Version 2 posted 09 November 2022

2,179

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1

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35 results in Matthew Sigman in Authors: Matthew Sigman

An Asymmetric Aromatic Finkelstein Reaction: A Platform for Remote Diarylmethane Desymmetrization

SMARTpy: A Python Package for the Generation of Cavity-Specific Steric Molecular Descriptors and Applications to Diverse Systems

Understanding Catalytic Enantioselective C-H Bond Oxidation at Nonactivated Methylenes Through Predictive Statistical Modeling Analysis

Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation

Development of a Simple Thioetherification of Heteroarene Electrophiles with Broad Scope via a Proton Transfer Dual Ioni-zation Mechanism

Predicting Success in Cu-Catalyzed C–N Coupling Reactions using Data Science

14N to 15N Isotopic Exchange of Nitrogen Heteroaromatics through Skeletal Editing

N-Ammonium Ylide Mediators for Selective Electrochemical C–H Oxidation

Data-driven multi-objective optimization tactics for catalytic asymmetric reactions

Generality-Oriented Optimization of Enantioselective Aminoxyl Radical Catalysis

35 results in Authors: Matthew Sigman