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Molecular Basis of Iterative C–H Oxidation by TamI, a Multifunctional P450 Monooxygenase from the Tirandamycin Biosynthetic Pathway

Sean A. Newmister, Kinshuk Raj Srivastava, Rosa V. Espinoza, Kersti Caddell Haatveit, Yogan Khatri, Rachel M. Martini, Marc Garcia-Borràs, Larissa M. Podust, Kendall N Houk, David H. Sherman

Version 1 posted 27 July 2020

478

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Catalysis

Working Paper

Biocatalytic asymmetric aldol addition into unactivated ketones

Samantha Bruffy, Anthony Meza, Jordi Soler, Tyler Doyon, Seth Young, Jooyeon Lim, Kathryn Huseth, Marc Garcia-Borràs, Andrew Buller

Version 1 posted 02 November 2023

749

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1

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Catalysis

Working Paper

Dual-Function Enzyme Catalysis for Enantioselective Carbon–Nitrogen Bond Formation

Zhen Liu, Carla Calvó-Tusell, Andrew Z. Zhou, kai chen, Marc Garcia-Borràs, Frances H. Arnold

Version 1 posted 20 April 2021

877

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1

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Catalysis

Working Paper

Directed Evolution Enables Dynamic Control of Transient Intermediates for Anti-Markovnikov Wacker-Tsuji-Type Oxidation of Unactivated Alkenes

Cindy Klaus, Jordi Soler, Grzegorz Kubik, Yosephine Gumulya, Yue Hui, Ella J. Watkins-Dulaney, Max-Luca Heitland, Marc Sommer, Alina Klein, Julia L. Kowal, Hartmut H. Niemann, Frances H. Arnold, Marc Garcia-Borràs, Stephan C. Hammer

Version 2 posted 17 September 2024

932

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Catalysis

Working Paper

Molecular Basis for Chemoselectivity Control in Oxidations of Internal Aryl-Alkenes Catalyzed by Laboratory Evolved P450s

Jordi Soler, Sebastian Gergel, Stephan Hammer, Marc Garcia-Borràs

Version 1 posted 25 January 2024

309

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Catalysis

Working Paper

Selective Enzymatic Oxidation of Silanes to Silanols

Susanne Bähr, Sabine Brinkmann-Chen, Marc Garcia-Borràs, John M Roberts, Dimitris E. Katsoulis, Kendall N Houk, Frances H. Arnold

Version 1 posted 18 March 2020

779

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1

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Catalysis

Working Paper

Engineering P450 TamI as an Iterative Biocatalyst for Selective Late-Stage C-H Functionalization and Epoxidation of Tirandamycin Antibiotics

Rosa V. Espinoza, Kersti Caddell Haatveit, S. Wald Grossman, Jin Yi Tan, Caylie A. McGlade, Yogan Khatri, Sean A. Newmister, Jennifer J. Schmidt, Marc Garcia-Borràs, John Montgomery, Kendall N Houk, David H. Sherman

Version 1 posted 16 March 2021

511

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Catalysis

Working Paper

Origin and Control of Chemoselectivity in Cytochrome c-Catalyzed Carbene Transfer into Si–H and N–H bonds

Marc Garcia-Borràs, S. B. Jennifer Kan, Russell D. Lewis, Allison Tang, Gonzalo Jiménez-Osés, Frances H. Arnold, Kendall N. Houk

Version 1 posted 25 February 2021

544

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Catalysis

Working Paper

A Biocatalytic Platform for Synthesis of Chiral α-Trifluoromethylated Organoborons

Xiongyi Huang, Marc Garcia-Borràs, Kun Miao, S. B. Jennifer Kan, Arjun Zutshi, K. N. Houk, Frances H. Arnold

Version 1 posted 26 September 2018

1,438

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Materials Chemistry

Working Paper

Regioselective access to orthogonal Diels-Alder C60 bis-adducts and tris-heteroadducts via avant-garde supramolecular mask strategy

Míriam Pujals, Tània Pèlachs, Carles Fuertes-Espinosa, Teodor Parella, Marc Garcia-Borràs, Xavi Ribas

Version 1 posted 25 January 2022

343

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14 results in Marc Garcia-Borràs in Authors: Marc Garcia-Borràs

Molecular Basis of Iterative C–H Oxidation by TamI, a Multifunctional P450 Monooxygenase from the Tirandamycin Biosynthetic Pathway

Biocatalytic asymmetric aldol addition into unactivated ketones

Dual-Function Enzyme Catalysis for Enantioselective Carbon–Nitrogen Bond Formation

Directed Evolution Enables Dynamic Control of Transient Intermediates for Anti-Markovnikov Wacker-Tsuji-Type Oxidation of Unactivated Alkenes

Molecular Basis for Chemoselectivity Control in Oxidations of Internal Aryl-Alkenes Catalyzed by Laboratory Evolved P450s

Selective Enzymatic Oxidation of Silanes to Silanols

Engineering P450 TamI as an Iterative Biocatalyst for Selective Late-Stage C-H Functionalization and Epoxidation of Tirandamycin Antibiotics

Origin and Control of Chemoselectivity in Cytochrome c-Catalyzed Carbene Transfer into Si–H and N–H bonds

A Biocatalytic Platform for Synthesis of Chiral α-Trifluoromethylated Organoborons

Regioselective access to orthogonal Diels-Alder C60 bis-adducts and tris-heteroadducts via avant-garde supramolecular mask strategy

14 results in Authors: Marc Garcia-Borràs