Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

Synthesis, Structure, and Reactivity of a Gallylene Derivative Bearing a Phenalenyl-Based Ligand

01 February 2023, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Phenalenyl-based N,N-bidentate ligand-stabilized monovalent gallium(I) 1 was synthesized and characterized. Compound 1 promotes the oxidative addition of I-I, Si-Cl, C-I, and S-S bonds and oxidative cyclization with various Pi-components. Compound 1 can also coordinate to a tungsten complex to form a gallium-tungsten bond.

Keywords

Gallylene
Main Group Chemistry
Phenalenyl
Oxidative Addition
Oxidative Cyclization

Supplementary materials

Title
Description
Actions
Title
Supplementary Information
Description
Electronic Supplementary Information
Actions
Title
CIF
Description
CCDC 2238068–2238073
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Version History

Feb 01, 2023 Version 2

Version Notes

Contents of Graphical Abstract was modified.

Metrics

514
310
1
Views
Downloads

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-jkhx3-v2
D O I: 10.26434/chemrxiv-2023-jkhx3-v2 [opens in a new tab]

Funding

Japan Society for the Promotion of Science
JP19K15564
Shorai Foundation for Science and Technology

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

Share