Synthesis, Structure, and Reactivity of a Gallylene Derivative Bearing a Phenalenyl-Based Ligand

01 February 2023, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Phenalenyl-based N,N-bidentate ligand-stabilized monovalent gallium(I) 1 was synthesized and characterized. Compound 1 promotes the oxidative addition of I-I, Si-Cl, C-I, and S-S bonds and oxidative cyclization with various Pi-components. Compound 1 can also coordinate to a tungsten complex to form a gallium-tungsten bond.

Keywords

Gallylene
Main Group Chemistry
Phenalenyl
Oxidative Addition
Oxidative Cyclization

Supplementary materials

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Description
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Supplementary Information
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Electronic Supplementary Information
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CIF
Description
CCDC 2238068–2238073
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