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Localization of Spiropyran Activation

preprint
revised on 27.12.2019 and posted on 30.12.2019 by Martha Grady, Cassandra Birrenkott, Preston A. May, ScottR. White, Jeffrey S. Moore, Nancy R. Sottos
Functionalization of planar and curved glass surfaces with spiropyran (SP) molecules and localized UV-induced activation of the mechanophore are demonstrated. Fluorescence spectra of UV-irradiated SP-functionalized surfaces reveal that increases in surface roughness or curvature produces more efficient conversion of the mechanophore to the open merocyanine (MC) form. Further, force-induced activation of the mechanophore is achieved at curved glass-polymer interfaces and not planar interfaces. Minimal fluorescence signal from UV-irradiated SP-functionalized planar glass surfaces precluded mechanical activation testing. Curved glass-polymer interfaces are prepared by SP functionalization of E-glass fibers, which are subsequently embedded in a poly(methyl methacrylate) (PMMA) matrix. Mechanical activation is induced through shear loading by a single fiber microbond testing protocol. In situ detection of SP activation at the interface is monitored by fluorescence spectroscopy.

Funding

ARO MURI W911NF-07-0409

NSF CMMI 11-61517

History

Email Address of Submitting Author

m.grady@uky.edu

Institution

University of Kentucky

Country

United States

ORCID For Submitting Author

0000-0002-1767-3653

Declaration of Conflict of Interest

The authors declare no competing financial interest

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in Langmuir

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