Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

03 June 2019, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A mechanism for Rh(I)-catalyzed asymmetric Suzuki-Miyaura coupling with racemic allyl halides is proposed based on a combination of experimental studies and quantum chemical calculations.

Keywords

Asymmetric Catalysis
Density Functional Calculations
Isotope Effects
Reaction Mechanisms
Rhodium

Supplementary materials

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SupportingInformation Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling
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