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Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

29 January 2020, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A mechanism for Rh(I)-catalyzed asymmetric Suzuki-Miyaura coupling with racemic allyl halides is proposed based on a combination of experimental studies and quantum chemical calculations.

Keywords

Asymmetric Catalysis
Density Functional Calculations
Isotope Effects
Reaction Mechanisms
Rhodium

Supplementary materials

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SupportingInformation Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling
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Now Published

Mechanistic investigation of Rh(i)-catalysed asymmetric Suzuki–Miyaura coupling with racemic allyl halides [opens in a new tab]
Lucy van Dijk, Ruchuta Ardkhean, Mireia Sidera, Sedef Karabiyikoglu, Özlem Sari, Timothy D. W. Claridge, Guy C. Lloyd-Jones, Robert S. Paton, Stephen P. Fletcher journal article
Nature Catalysis , Volume 4, Issue 4
Online publication date: Apr 05, 2021

Version History

Jan 29, 2020 Version 2

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.8208617.v2
D O I: 10.26434/chemrxiv.8208617.v2 [opens in a new tab]

Funding

EP/N022246/1
EP/L015838/1
EP/L015722/1
ACI-1532235
ACI-1532236

Author’s competing interest statement

Oxford University Innovation has filed a patent application (PCT/GB2016/051612) with S.P.F. and M.S. named as inventors. The remaining authors declare no competing financial interests.

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