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Organic Chemistry

Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

Abstract

A mechanism for Rh(I)-catalyzed asymmetric Suzuki-Miyaura coupling with racemic allyl halides is proposed based on a combination of experimental studies and quantum chemical calculations.

Content

Supplementary material

SupportingInformation Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling

Version History

Jan 29, 2020 Version 2
Jun 03, 2019 Version 1

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License

CC logo BY logo NC logo ND logo
The content is available under CC BY NC ND 4.0 License CreativeCommons.org [opens in a new tab]

DOI

10.26434/chemrxiv.8208617.v2
D O I: 10.26434/chemrxiv.8208617.v2 [opens in a new tab]

Funding

EP/N022246/1
EP/L015838/1
EP/L015722/1
ACI-1532235
ACI-1532236

Author’s competing interest statement

Oxford University Innovation has filed a patent application (PCT/GB2016/051612) with S.P.F. and M.S. named as inventors. The remaining authors declare no competing financial interests.

Keywords

Asymmetric Catalysis
Density Functional Calculations
Isotope Effects
Reaction Mechanisms
Rhodium

Publication

This content is an early or alternative research output and has not been peer-reviewed at the time of posting.