Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

29 January 2020, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A mechanism for Rh(I)-catalyzed asymmetric Suzuki-Miyaura coupling with racemic allyl halides is proposed based on a combination of experimental studies and quantum chemical calculations.

Keywords

Asymmetric Catalysis
Density Functional Calculations
Isotope Effects
Reaction Mechanisms
Rhodium

Supplementary materials

Title
Description
Actions
Title
SupportingInformation Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling
Description
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Now Published

Mechanistic investigation of Rh(i)-catalysed asymmetric Suzuki–Miyaura coupling with racemic allyl halides [opens in a new tab]
Lucy van Dijk, Ruchuta Ardkhean, Mireia Sidera, Sedef Karabiyikoglu, Özlem Sari, Timothy D. W. Claridge, Guy C. Lloyd-Jones, Robert S. Paton, Stephen P. Fletcher journal article
Nature Catalysis , Volume 4, Issue 4
Online publication date: Apr 05, 2021

Version History

Jan 29, 2020 Version 2

Metrics

5,998
1,449
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
NC logo
NC
ND logo
ND
The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.8208617.v2
D O I: 10.26434/chemrxiv.8208617.v2 [opens in a new tab]

Funding

EP/N022246/1
EP/L015838/1
EP/L015722/1
ACI-1532235
ACI-1532236

Author’s competing interest statement

Oxford University Innovation has filed a patent application (PCT/GB2016/051612) with S.P.F. and M.S. named as inventors. The remaining authors declare no competing financial interests.

Share