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An Epoxide Intermediate in Glycosidase Catalysis

Lukasz F. Sobala, Gaetano Speciale, Sha Zhu, Lluís Raich, Natalia Sannikova, Andrew J. Thompson, ZALIHE HAKKI, Dan Lu, Saeideh Shamsi Kazem Abadi, Andrew R. Lewis, Victor Rojas-Cervellera, Ganeko Bernardo-Seisdedos, Yongmin Zhang, Oscar Millet, Jesús Jiménez-Barbero, Andrew J. Bennett, Matthieu Sollogoub, Carme Rovira, Gideon J. Davies, Spencer Williams

Version 1 posted 04 September 2019

795

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Biological and Medicinal Chemistry

Working Paper

The Catalytic Acid-Base in GH109 Resides in a Conserved GGHGG Loop and Allows for Comparable α-Retaining and β-Inverting Activity in an N-Acetylgalactosaminidase from Akkermansia Muciniphila

David Teze, Bashar Shuoker, Evan Kirk Chaberski, Ruth Sonja Kunstmann, Folmer Fredslund, Günther H.J. Peters, Eva Nordberg Karlsson, Ditte Hededam Welner, Maher Abou Hachem

Version 1 posted 21 October 2019

707

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Biological and Medicinal Chemistry

Working Paper

In Vitro Reconstitution and Kinetic Characterization of the Essential Condensation Enzymes Involved in Prodiginine and Tambjamine Biosynthesis

Katherine J. Picott, Julie A. Deichert, Ella M. deKemp, Avena Ross

Version 1 posted 19 April 2019

807

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Catalysis

Working Paper

Site-selective deuteration of amino acids through dual protein catalysis

Tyler Doyon, Andrew Buller

Version 1 posted 09 March 2022

444

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Inorganic Chemistry

Working Paper

A Dynamic Substrate is Required for MhuD-catalyzed Degradation of Heme to Mycobilin

Biswash Thakuri, Bruce O'Rourke, Amanda Graves, Matthew Liptak

Version 4 posted 05 March 2021

840

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Catalysis

Working Paper

Defining the molecular architecture, metal dependence, and distribution of metal-dependent class II sulfofructose-1-phosphate aldolases

Mahima Sharma, Arashdeep Kaur, Niccolay Madiedo Soler, James Lingford, Ruwan Epa, Ethan Goddard-Borger, Gideon Davies, Spencer Williams

Version 1 posted 08 August 2023

229

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Catalysis

Working Paper

Glutamate “flick” enables proton tunneling during fast redox biocatalysis

Stephen B. Carr, Wangzhe Li, Kin Long Wong, Rhiannon M. Evans, Sophie E. T. Kendall-Price, Kylie A. Vincent, Philip A. Ash

Version 1 posted 06 May 2024

477

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Catalysis

Working Paper

Mechanism of a Novel Metal-Free Carbonic Anhydrase

Shalini Yadav, Surajit Kalita, Kshatresh Dubey

Version 1 posted 18 October 2024

215

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Theoretical and Computational Chemistry

Working Paper

The Catalytic Mechanism of the Plastic-Degrading Enzyme Urethanase UMG-SP2

Pedro Paiva, Luís M. C. Teixeira, Ren Wei, Weidong Liu, Jens P. Morth, Peter Westh, Allan R. Petersen, Martin B. Johansen, Andreas Sommerfeldt, Alexander Sandahl, Daniel E. Otzen, Pedro A. Fernandes, Maria J. Ramos

Version 1 posted 06 August 2024

628

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Catalysis

Working Paper

Mechanistic elucidation and stereochemical consequences of alternative binding of alkenyl substrates by engineered arylmalonate decarboxylase

Elske van der Pol, Thomas Schlatzer, Gyula Hoffka, Bruno di Geronimo, Johannes Eder, Anna Katharina Schweiger, Marianna Karava, Dominik Gross, Roland Fischer, Daniel Kracher, Romas Kazlauskas, Kenji Miyamoto, Shina Caroline Lynn Kamerlin, Rolf Breinbauer, Robert Kourist

Version 2 posted 25 June 2025

486

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10 results in Enzyme mechanism in Keywords: Enzyme mechanism

An Epoxide Intermediate in Glycosidase Catalysis

The Catalytic Acid-Base in GH109 Resides in a Conserved GGHGG Loop and Allows for Comparable α-Retaining and β-Inverting Activity in an N-Acetylgalactosaminidase from Akkermansia Muciniphila

In Vitro Reconstitution and Kinetic Characterization of the Essential Condensation Enzymes Involved in Prodiginine and Tambjamine Biosynthesis

Site-selective deuteration of amino acids through dual protein catalysis

A Dynamic Substrate is Required for MhuD-catalyzed Degradation of Heme to Mycobilin

Defining the molecular architecture, metal dependence, and distribution of metal-dependent class II sulfofructose-1-phosphate aldolases

Glutamate “flick” enables proton tunneling during fast redox biocatalysis

Mechanism of a Novel Metal-Free Carbonic Anhydrase

The Catalytic Mechanism of the Plastic-Degrading Enzyme Urethanase UMG-SP2

Mechanistic elucidation and stereochemical consequences of alternative binding of alkenyl substrates by engineered arylmalonate decarboxylase

10 results in Keywords: Enzyme mechanism