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Catalysis

Working Paper

Molecular and Supported Ti(III)–Alkyls: Efficient Ethylene Polymerization Driven by π-Character of Metal-Carbon Bonds and Back Donation from a Singly Occupied Molecular Orbital

Anton Ashuiev, Florian Allouche, Nino Wili, Keith Searles, Daniel Klose, Christophe Copéret, Gunnar Jeschke

Version 1 posted 24 July 2020

568

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Catalysis

Working Paper

Spectroscopic Signature and Structure of Active Sites in Ziegler-Natta Polymerization Catalysts revealed by Electron Paramagnetic Resonance

Anton Ashuiev, Matthieu Humbert, David Gajan, Sebastien Norsic, Jan Blahut, Keith Searles, Daniel Klose, Anne Lesage, Guido Pintacuda, Jean Raynaud, Vincent Monteil, Christophe Copéret, Gunnar Jeschke

Version 3 posted 25 February 2021

762

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Catalysis

Working Paper

CH4-to-CH3OH on Mononuclear Cu(II) Sites Supported on Al2O3: Structure of Active Sites from Electron Paramagnetic Resonance

Jordan Meyet, Anton Ashuiev, Gina Noh, Mark Newton, Daniel Klose, Keith Searles, Alexander van Bavel, Andrew Horton, Gunnar Jeschke, Jeroen A. van Bokhoven, Christophe Copéret

Version 2 posted 17 February 2021

819

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Inorganic Chemistry

Working Paper

Geometry and Electronic Structure of Yb(III)[CH(SiMe3)2]3 from EPR and solid-state NMR augmented by Computations

Anton Ashuiev, Florian Allouche, Md. Ashraful Islam, José P. Carvalho, Kevin J. Sanders, Matthew P. Conley, Daniel Klose, Giuseppe Lapadula, Michael Wörle, Dirk Baabe, Marc D. Walter, Andrew J. Pell, Christophe Copéret, Gunnar Jeschke, Guido Pintacuda, Richard A. Andersen

Version 2 posted 17 November 2023

759

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Inorganic Chemistry

Working Paper

Active Sites in Cr(III)-based Ethylene Polymerization Catalysts from Machine Learning-Supported XAS and EPR Spectroscopy

Anton Ashuiev, Anna Giorgia Nobile, David Trummer, Daniel Klose, Sergey Guda, Olga V. Safonova, Christophe Copéret, Alexander Guda, Gunnar Jeschke

Version 1 posted 08 September 2023

216

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Catalysis

Working Paper

Union Carbide Polymerization Catalysts: from Uncovering Active Site Structures to Designing Molecularly-Defined Analogs

David Trummer, Anna Nobile, Pierre-Adrien Payard, Anton Ashuiev, Yuya Kakiuchi, Daniel Klose, Gunnar Jeschke, Christophe Copéret

Version 2 posted 21 July 2022

798

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Catalysis

Working Paper

Branch-selective Olefin Hydroaminoalkylation from Ti(III)–Al Bimetallic Intermediates evidenced by EPR Hyperfine Spectroscopy and DFT Calculations

Mariko Inoue, Julian Stropp, Anton Ashuiev, Yuya Kakiuchi, Pierre-Adrien Payard, Tokiya Teraishi, Mai Mizukami, Hayato Tsurugi, Daniel Klose, Christophe Copéret, Kazushi Mashima

Version 1 posted 10 October 2024

246

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7 results in Anton Ashuiev in Authors: Anton Ashuiev

Molecular and Supported Ti(III)–Alkyls: Efficient Ethylene Polymerization Driven by π-Character of Metal-Carbon Bonds and Back Donation from a Singly Occupied Molecular Orbital

Spectroscopic Signature and Structure of Active Sites in Ziegler-Natta Polymerization Catalysts revealed by Electron Paramagnetic Resonance

CH4-to-CH3OH on Mononuclear Cu(II) Sites Supported on Al2O3: Structure of Active Sites from Electron Paramagnetic Resonance

Geometry and Electronic Structure of Yb(III)[CH(SiMe3)2]3 from EPR and solid-state NMR augmented by Computations

Active Sites in Cr(III)-based Ethylene Polymerization Catalysts from Machine Learning-Supported XAS and EPR Spectroscopy

Union Carbide Polymerization Catalysts: from Uncovering Active Site Structures to Designing Molecularly-Defined Analogs

Branch-selective Olefin Hydroaminoalkylation from Ti(III)–Al Bimetallic Intermediates evidenced by EPR Hyperfine Spectroscopy and DFT Calculations

7 results in Authors: Anton Ashuiev