Quasi-Two-Dimensional Phases of a Non-Fullerene Acceptor by Interfacial Assembly

03 June 2025, Version 1

Abstract

Supramolecular organization governs the structure and optoelectronic properties of organic thin films. This study shows that films based on the non-fullerene acceptor Y6 can be precisely structured via assembly at the air-water interface. Theoretical cross-sectional areas, Langmuir isotherms, and Brewster angle microscopy reveal that Y6, despite its complex structure, is sufficiently amphiphilic to form well-defined two-dimensional layers. Mechanical annealing through compression-expansion (CE) cycles systematically improves structural uniformity, as evidenced by narrower in-situ detected fluorescence spectra. Repeated CE-cycles also shift the maximum of the compressional modulus towards denser packing. Compared to spin-cast films, Langmuir-Schaefer (LS) layers exhibit a significantly reduced Stokes shift, suggesting less reorganization after photoexcitation and thus a higher supramolecular order. Organic thin-film transistors (OTFTs) fabricated using the LS technique achieve mobilities comparable to those of spin-cast films, despite being substantially thinner (≤ 3 nm, determined by atomic force microscopy), thus requiring considerably less material. Notably, Y6-LS OTFTs outperform previously reported polymer-based LS-OTFTs by one order of magnitude in charge carrier mobility. This work highlights the potential of interfacial assembly for thin film fabrication and underscores the advantages of mechanical annealing and in-situ spectroscopy to enhance the performance of organic optoelectronic devices.

Keywords

Langmuir layers
Ultrathin film
optoelectronics
morphology
non-fullerene acceptor

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.