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Synthesis of a Mixed Bis(imino)acenaphthene (BIAN) Ligand Using Aluminum Transfer Reagents

03 April 2025, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Aminoalane and iminoalane transfer reagents are employed in the synthesis of ketoimines based upon an acenaphthene scaffold. One of the ketoimine species is subsequently used as a precursor for the synthesis of a mixed-BIAN ligand which features both perfluorophenyl- and tert-butyl substituents.

Keywords

BIAN
aluminum
synthesis

Supplementary materials

Title
Description
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Computational Details
Description
Tables of isomerization and HOMO-LUMO gap calculation results
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Structure 1
Description
cif file of structure 1
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Structure 2
Description
cif file of structure 2
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Structure 4
Description
cif file of structure 4
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Mono tBu structure
Description
cif file of mono tBu structure
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Structure 5
Description
cif file of structure 5
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Version History

Apr 03, 2025 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2025-zqhfk
D O I: 10.26434/chemrxiv-2025-zqhfk [opens in a new tab]

Funding

Welch Foundation
F-003
Welch Foundation
D-1807
NSF
CHE-0840494

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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