Chemical Transformations of Donor-acceptor Cyclopropanes With Conjugated Diacetylenes in the Presence of GaCl3

28 March 2025, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The reaction of 1,2-zwitterionic complexes of 2-arylcyclopropane-1,1-dicarboxylates (ACDC), generated using gallium trichloride, with symmetrically substituted diacetylenes was studied. The reaction occurs via a cascade addition/annulation/elimination pathway involving both triple bonds to form substituted 1,1'-binaphthalenes in up to 50% yields. The regioselectivity of this process was studied, and it was shown that binaphthalenes formed exclusively as 1,1'-regioisomers.

Keywords

Donor–acceptor cyclopropanes
Vinyl carbocations
Addition/annulation reactions
Gallium trichloride
binaphthalenes

Supplementary materials

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Supporting Info
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The file contain the synthetic procedure and spectroscopic data of obtained products.
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