One-dimensional Metallicity and π-band Superconductivity in Rhodizonate Radical Pancakes

Computational exploration of condensed phases made of potassium and carbon monoxide leads to predictions of stable salts com-posed of cyclic six-membered oxocarbon anions and K+ cations, Kn(C6O6)m. The states of reduction in these systems are wide rang-ing, with C6O6 molecules formally reduced by -2, -3, -3.5 and -6, in semi-conducting and metallic phases. Special attention is paid to K3C6O6, in which triply charged radical anions stack closely and equidistantly in one-dimension. Equidistant interactions of radi-cals are exceedingly rare and typically unstable due to spontaneous symmetry breaking, Peierls or Jahn-Teller distortion. The nota-ble exception of K3C6O6 is explained by inter-ring multi-center bonding, also known as pancake bonding, in combination with large ionic repulsion. This fascinating interplay of interactions facilitates an exceptionally high density of states at the Fermi level and leads us to predictions of extreme metallicity, a negative temperature coefficient of resistivity, and rare π-band superconductivity at ambient conditions of pressure. These predictions reinvigorate the search for new organic conductors and superconductors using molecular design of metallic salts.