Sustainable Synthesis of Semicrystalline Polymers: Green Chemistry Approaches and Applications

The increasing demand for sustainable materials has driven the development of eco-friendly semicrystalline polymers through green chemistry approaches. This review explores the latest advancements in sustainable synthesis methods, including bio-based monomers, CO₂-based polymerization, solvent-free techniques, and enzymatic catalysis. Key properties such as thermal stability, mechanical performance, and biodegradability are analyzed, along with a comparative assessment of green semicrystalline polymers versus their conventional counterparts. Challenges related to scalability, cost-effectiveness, and maintaining crystallinity are discussed, highlighting future research directions for advancing sustainable polymer technologies. This study aims to provide insights into the evolving landscape of environmentally friendly semicrystalline polymers and their potential applications in diverse industries.