Ultrasound-Driven Radical Expansion: Unlocking Novel Chemical Pathways

14 February 2025, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

This study investigates the potential of ultrasound-induced radical generation to accelerate chemical reactions, focusing on the decomposition of hydrogen peroxide (H₂O₂). High-frequency ultrasound creates cavitation bubbles that collapse to produce hydroxyl radicals (•OH), significantly enhancing reaction rates. Our results demonstrate that this approach increases the decomposition rate of H₂O₂ by 400% compared to conventional methods. The implications extend to various applications, including optimizing chemotherapy drug activation and improving wastewater treatment through advanced oxidation processes. Given its scalability and cost-effectiveness, ultrasound-driven radical chemistry has the potential to transform industrial and scientific processes.

Keywords

Ultrasound
Sonoluminescence
Sonochemistry
Radicals
Decomposition

Supplementary materials

Title
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Title
Decomposition Rates of Hydrogen Peroxide with KI and Ultrasound Vibration
Description
This dataset presents the decomposition rates of hydrogen peroxide (H₂O₂) with potassium iodide (KI), both with and without ultrasound vibration, observed at 1, 3, 5, and 10 minutes. The rate is measured by the number of gas bubbles produced, indicating the reaction speed. Hydrogen Peroxide + KI: The decomposition rate is consistent at 10 bubbles per minute (0.17 bubbles/second) across all time intervals. Hydrogen Peroxide + KI + Ultrasound Vibration: With ultrasound vibration, the rate increases significantly to 240 bubbles per minute (40 bubbles/second) at 3, 5, and 10 minutes. This dataset highlights the accelerated decomposition of hydrogen peroxide when ultrasound is applied, suggesting its potential role in enhancing chemical reactions through cavitation effects.
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