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Ruthenium(II) complexes with photoswitchable and photoejectable ligands

04 February 2025, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A ruthenium(II) complex with a photoswitchable arylazopyrazole ligand is reported. Under irradiation a combination of photoisomerisation and photoejection of the ligand occurs.

Keywords

ruthenium
photophysics
photochemistry
photoswitching

Supplementary materials

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Description
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Supporting information
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All the experimental, spectroscopic and other additional data
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Data for S1 of the SI
Description
Data for S1 of the SI
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Data for S2 of the SI
Description
Data for S2 of the SI - photoswitching data
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Data for S3 of the SI
Description
Data for S3 of the SI - UV-vis absorption spectra
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Data for S4 of the SI
Description
Data for S4 of the SI - NMR data
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Data for S5 of the SI
Description
Data for S5 of the SI - ESI-MS data
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Version History

Feb 04, 2025 Version 1

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The content is available under CC BY NC 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2025-3sffc
D O I: 10.26434/chemrxiv-2025-3sffc [opens in a new tab]

Funding

Australian Research Council
DP220101847

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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