Abstract
Perovskite solar cells are becoming more efficient and stable day by day due to continuous
research. The commercial use of the cells is, however, being constrained by various obstacles.
These include material costs, absorber material toxicity, cell efficiency, and cell stability. To solve
these issues, new materials and solar cell architectures should be investigated. In this study, we
investigate the use of V2O5 as a novel hole transport material (HTM) for non-toxic perovskite solar
cells. Our proposed cell structure incorporates V2O5 as the HTM, CsSnI3 as the absorber, and WS2
as the electron transport material (ETM). Through simulation and optimization, we achieve an
optimal efficiency of 24.71% with an open circuit voltage (Voc) of 0.8489V, a short circuit current
(Jsc) of 35.601mA/cm2, and a fill factor (FF) of 81.75%. These results highlight the potential of
V2O5 as a promising HTM for enhancing the performance of non-toxic perovskite solar cells.