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Abstract
Novel homoleptic and heteroleptic cationic germylene-gold(I) complexes were synthesized through the insertion of dialkyl- and acyclic diamino- germylenes into Au-Cl bonds. Structural characterization and DFT calculations revealed the distinct π-back donation and dihedral angles, providing quantitative insights into the stability of germylene ligands in gold(I) complexes and expanding the boundaries of coordination chemistry.
Supplementary materials
Title
Synthesis and Structural Insights into Homoleptic and Heteroleptic Cationic Germylene Gold(I) Complexes
Description
Experimental details are provided in this Supplementary Information.
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