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Side-on phosphinoboryl platinum(II) complexes

26 November 2024, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

In this work, we report the synthesis of the first phosphinoboryl transition metal complexes, featuring a direct covalent bond between boron and phosphorus atoms. The oxidative addition of bromo(phosphino)boranes to platinum(0) compounds enabled the formation of platinum(II) complexes with unprecedented side-on coordination of the boryl ligand.

Keywords

boron
phosphorus
platinum
boryl complexes

Supplementary materials

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Experimental, crystallographic, spectroscopic and computational details.
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Version History

Nov 26, 2024 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-30x8x
D O I: 10.26434/chemrxiv-2024-30x8x [opens in a new tab]

Funding

Gdańsk University of Technology
DEC-2/2021/IDUB/V.6/Si
Gdańsk University of Technology
Minigrant No. 037741

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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