Classification and Identification of Facet and Edge specific γ-Al2O3 Surface Sites from 1H/27Al NMR Cross-Signatures and DFT modelling

γ-Al2O3 is used as both catalyst or support for catalytic active phases. The properties of γ-Al2O3 have been ascribed to specific surface sites, with varying Al coordination number, acidity and basicity, depending on the morphology of the material. Here, we combine surface-specific 27Al{1H} 2D high field NMR (28.2T, 1.2 GHz for 1H frequency) at fast MAS (50kHz) to observe four main distinct families of surface Al-OH sites. Comparing the measured NMR signatures (27Al δiso, CQ and 1H δiso) to computed values from a large range of structural DFT models enables to identify specific edge and facet Al-OH surface sites in γ-Al2O3, including a distinct [4]Al-OH site with an unprecedented CQ approaching 18MHz. This molecular-level description of alumina surfaces opens new opportunities to understand its unique properties, such as the stabilization of small particles down to single atoms, central to catalytic processes.