Advancing Sustainable Ammonia Production via Solventless, Robust, and Thermally Conductive Absorbents

Sorption-based low-pressure green ammonia synthesis using supported metal halide salts enables efficient interconversion between hydrogen and ammonia, allowing the high hydrogen density and well-established transportation network of ammonia to be used for green energy storage. Magnesium chloride supported on silica gel (MgCl2/SiO2) sorbent has been the subject of much investigation owing to its high capacity, selectivity, and reversibility at temperatures close to reactor conditions; however, MgCl2/SiO2 suffers from low thermal conductivity, which complicates absorber design at larger scales and prolongs absorption-desorption cycle times. We present a scalable, solventless method for supporting MgCl2 on thermally conductive aluminum fibers (MgCl2/Al) - a thermally conductive ammonia sorbent with a high working capacity of 220 mgNH3/gabsorbent. Although the solventless synthesis causes variance in initial-cycle pressure drop and capacity, we show that this stabilizes after cycling. The high thermal conductivity of MgCl2/Al allows for rapid absorption-desorption cycles, enabling easier scale-up. MgCl2/Al also maintains its cyclic capacity up to 50 cycles without any signs of degradation.