A Multiresonant Thermally Activated Delayed Fluorescent Dendrimer with Intramolecular Energy Transfer: Application for Efficient Host-Free Green Solution-Processed Organic Light-emitting Diodes

The development of narrowband emissive, bright, and stable solution-processed organic light-emitting diodes (SP-OLEDs) remains a challenge. Here, we present a strategy that merges within a single emitter a TADF sensitizer responsible for exciton harvesting and a MR-TADF motif that provides bright and narrowband emission. This emitter design also shows strong resistance to aggregate formation and aggregation-cause quenching. It is based on a known MR-TADF emitter DtBuCzB with a donor-acceptor TADF moiety consisting of either tert-butylcarbazole donors (tBuCzCO2HDCzB) or second-generation carbazole-based donor dendrons (2GtBuCzCO2HDCzB) and a benzoate acceptor. The TADF moiety acts as an exciton harvesting antenna and transfer these excitons via Förster resonance energy transfer to the MR-TADF emissive core. The SP-OLEDs with 2GtBuCzCO2HDCzB and tBuCzCO2HDCzB thus showed very high maximum external quantum efficiencies (EQEmax of 27.9 and 22.0%) and minimal efficiency roll-off out to 5000 cd m-2.