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Abstract
We present the synthesis of 16 unprecedented sulfonyl fluoride functionalized 2-aminothiazoles in good to excellent yields. The transformation is simple to perform, tolerant of a wide range of functionality and regioselective for a single product. Additionally, we showcase the diversification of the novel 2-aminothiazoles through SuFEx click chemistry. Finally, we propose a plausible stepwise reaction mechanism.
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