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Probing the Reactivity of Bimetallic Alkylmagnesium Complexes Using a Rigid and Dinucleating Naphthyridine-Based Ligand

21 August 2024, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The synthesis, characterisation and reactivity of a Mg2(n-Bu)2 complex bound by a rigid and dinucleating ligand is described. Supported by calculations we detail the effects of nuclearity and coordinative saturation of Mg2(n-Bu)2 complexes on reactivity and demonstrate amine-borane dehydrogenation at decreased temperatures due to the enforced proximity of the Mg-centres.

Keywords

alkylmagnesium
bimetallic
Naphthyridine

Supplementary materials

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Electronic Supporting information containing experimental and computational details, and spectra
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Version History

Aug 21, 2024 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-fpkp6
D O I: 10.26434/chemrxiv-2024-fpkp6 [opens in a new tab]

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) declare that they have sought and gained approval from the relevant ethics committee/IRB for this research and its publication.

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