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Gabriel Synthesis of Aminomethyl-Bicyclo[1.1.0]butanes

08 August 2024, Version 1

Abstract

The reaction of iodo-bicyclo[1.1.1]pentanes with potassium phthalimide yields phthalimide-substituted bicyclo[1.1.0]butanes (BCBs), which upon hydrazinolysis afford the corresponding aminomethyl-BCB products.

Keywords

BCP
BCB
Bicyclobutanes
Bicyclo[1.1.0]butanes
Bicyclo[1.1.1]pentanes

Supplementary materials

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Description
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Electronic Supporting Information
Description
Procedures, NMR spectra, X-ray structures
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Version History

Aug 08, 2024 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-8xc0d
D O I: 10.26434/chemrxiv-2024-8xc0d [opens in a new tab]

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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