Strategies and Tactics for Site Specific Deuterium Incorporation at Each Available Carbon Atom of a-Pinene

08 August 2024, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The development of several unique strategies and tactics for the synthesis of a-pinene isotopologues that has culminated in access to all eight possible isomers with deuterium incorporated selectively at each available carbon atom is described. Access to this library of isotopologues provides new tools to more fully investigate the atmospheric autoxidation of a-pinene, a complex process that plays a major role in the formation of secondary organic aerosol (SOA) in the Earth’s atmosphere.

Supplementary materials

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Supporting Information
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Experimental procedures, spectroscopic data
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