Unlocking Novel P-Containing Scaffolds by Exploration of a Photocatalyzed Halogen-Bonding-Assisted EDA-SET Reaction.

The synthesis of new heterocyclic structures is a challenging endeavor in organic chemistry. It requires the development of innovative methods that can generate novel frameworks, thereby allowing exploration of uncharted chemical spaces for potential applications. In this context, Halogen-Bonding-Assisted EDA-SET strategy presents a promising and efficient approach. In our study, we propose employing this strategy to facilitate the exploration of diverse phosphorus-based scaffolds, which hold significant potential for future research endeavors. By leveraging the EDA strategy, we aim to unlock new opportunities and advance the field of phosphorus-based chemistry.