Evaluation of Hydrogen Evolution Activity by Bubbles Growth Rates as Descriptor

Evaluation of the electrocatalytic behavior in the high current density region is critical toward the applications in the industrial water electrolysis system. Here, we utilized the bubble growth rate as descriptor for evaluation of hydrogen evolution reaction. Ag electrode was selected as a model electrode. Pressure-controlled cell was used for the evaluation of the bubble behavior under the wider range in the overpotential. Hydrogen bubble evolution behavior was evaluated by video observation under electrochemical potential control. Even in the presence of the complex processes such as nucleation, growth and detachment of the bubbles, the hydrogen evolution behavior is evaluated with respect to the classical Tafel analyses even in high overpotential region. These analyses provide the methods for the rapid screening toward the material discovery of the green hydrogen production in high current density region.