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Abstract
A modular, operationally practical Ni(0)/silane alkene isomerization system has been developed with air-stable reagents. A diverse array of functional groups are tolerated, including aryl bromides, aromatic heterocycles, tertiary amines, and α,β-unsaturated amides. Mechanistic experiments support a Ni–H insertion/elimination pathway.
Supplementary materials
Title
Kascoutas ChemRxiv 2024
Description
Descriptions of materials, methods, and experimentals. Figures of time-course studies and characterization spectra.
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