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T-Shaped Nickel Metalloradical Bearing a Phenalenyl-Based Tridentate Ligand

03 May 2024, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A T-shaped nickel(I) complex 1 bearing a phenalenyl-based tridentate ligand was synthesized. The electronic and spin struc-tures of 1 were elucidated through electronic absorption spectra, ESR, and XAFS measurements. Additionally, the metallo-radical reactivity of 1 toward diphenyl disulfide and alkyl halides was also demonstrated.

Keywords

metalloradical
nickel(I) complex
XAFS
phenalenyl

Supplementary materials

Title
Description
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Title
Supporting Information
Description
Detailed experimental procedures, characterization of new com-pounds, and computational details.
Actions
Title
CIF
Description
CIF for Complex 4
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Version History

May 03, 2024 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-39t04
D O I: 10.26434/chemrxiv-2024-39t04 [opens in a new tab]

Funding

Japan Society for the Promotion of Science
JP23K13729, JP24H01852, JP24H02217, JP24H02206, JP24H02207
Shorai Foundation for Science and Technology

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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