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Triptycene-based diiron(II) mesocate: spin-crossover in solution

05 April 2024, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T1/2 at 243 K (Evans method).

Keywords

triptycene
mesocate
dimetallic complex
spin-crossover

Supplementary materials

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Version History

Apr 05, 2024 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-bqd0k
D O I: 10.26434/chemrxiv-2024-bqd0k [opens in a new tab]

Funding

Ministero dell'Università e della Ricerca

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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