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Estimation of the rate constants for the radical addition of trifluoromethyl radical to vinyl triflates

06 March 2024, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The rate constants for the radical addition of trifluoromethyl radical have been determined by applying competition kinetics at a single concentration point. The rate constants range from 4.1 × 106 to 5.6 × 106 M−1 s−1 and depend on the electronic properties of the benzene rings.

Keywords

radical
vinyl triflate
trifluoromethylation
rate constant

Supplementary materials

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Version History

Mar 06, 2024 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-bgtkr
D O I: 10.26434/chemrxiv-2024-bgtkr [opens in a new tab]

Funding

the New Energy and Industrial Technology Development Organization (NEDO)
21502091-0
Grant-in-Aid for Scientific Research (C)
22K05116

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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