Estimation of the rate constants for the radical addition of trifluoromethyl radical to vinyl triflates

06 March 2024, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

The rate constants for the radical addition of trifluoromethyl radical have been determined by applying competition kinetics at a single concentration point. The rate constants range from 4.1 × 106 to 5.6 × 106 M−1 s−1 and depend on the electronic properties of the benzene rings.

Keywords

radical
vinyl triflate
trifluoromethylation
rate constant

Supplementary materials

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