Dataset for the synthesis and characterization of disordered metallic carbon materials from graphene edge chemistry

This dataset provides a comprehensive account of the intricate processes involved in the rational design, synthesis, and characterization of anisotropic metallic carbon materials. The materials were derived through the hydrolytic oxidation of graphene sheets, followed by meticulous self-assembly and mild annealing. The resulting products are highly percolated carbon networks, preserving the essential basal area of the source graphene. Structured into various sections, this dataset aims to furnish detailed insights crucial for supporting extensive investigations into these carbon materials. Section S1 delves into simulations that elucidate the reactivity of hydroxyl radicals in the hydrolytic oxidation process, pinpointing optimal conditions for their selective use in edge-hydrolysis of graphene. Additionally, it explores the molecular dynamics of edge-hydrolyzed graphene sheets, unraveling their self-assembly behavior and the formation of highly ordered films. Section S2 meticulously describes the source materials and optimal protocols, aligning with insights gained from simulations. In Section S3, the dataset explores the impact of synthesis protocols on the processability of hydrolyzed graphene and anticipates potential applications. Sections S4 to S7 present detailed characterization protocols, meticulously divided into morphology, composition, mechanical properties, and thermal/electronic transport, ensuring the inclusion of all essential details for reproducibility in core characterizations. Finally, Section S8 presents a table summarizing the general properties of the final annealed metallic carbon film (G0). This dataset thus serves as a valuable resource, providing a robust foundation for in-depth studies and fostering a comprehensive understanding of the multifaceted aspects of anisotropic metallic carbon materials.