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Rare-Earth Acetates as Alternative Precursors for Rare-Earth Cluster-Based Metal–Organic Frameworks

13 February 2024, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

RE-UiO-66 analogues are synthesized using RE acetates as precursors for the first time. These MOFs are fully characterized and the influence of the precursor on the materials obtained is studied. Additionally, the influence of water on the yield of the syntheses and the quality of the materials is explored.

Keywords

metal-organic frameworks
MOFs
rare-earths
RE-MOFs
acetate precursors
RE-UiO-66

Supplementary materials

Title
Description
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Title
Supporting Information
Description
Synthetic procedures, SEM, NMR, DRIFTS, TGA
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Version History

Feb 13, 2024 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-z6hsj
D O I: 10.26434/chemrxiv-2024-z6hsj [opens in a new tab]

Funding

Natural Sciences and Engineering Research Council of Canada
RGPIN-2018-04388

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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