Which Flavor of 9,10-Bis(phenylethynyl)anthracene is Best for Perovskite-Sensitized Triplet-Triplet Annihilation?

23 January 2024, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A lack of viable solid-state annihilators is the greatest hurdle in perovskite-sensitized triplet-triplet annihilation upconversion (UC). Unfavorable singlet and triplet energy surfaces in solid state have limited successful implementation of many conventional solution-based annihilators. To date, rubrene is still the best performing annihilator; however, this comes at the cost of a small apparent anti-Stokes shift. To this point, anthracene derivatives are promising candidates to increase the apparent anti-Stokes shift. The green glowstick dye 9,10-(bisphenylethynyl)anthracene (BPEA) and its derivatives have already shown great promise in solution-based UC applications. Due to favorable band alignment of the perovskite and energy levels, it is conceivable that a wide variety of BPEA derivatives could be compatible with the perovskite-based UC system. Here, we investigate the properties of BPEA and its derivatives 1-chloro-9,10-(bisphenylethynyl)anthracene and 2-chloro-9,10-(bisphenylethynyl)anthracene. Despite similar optical properties in solution, the different molecules exhibit vastly different properties in thin films. UC studies in lead halide perovskite/BPEA bilayer devices demonstrate the importance of intermolecular coupling on the resulting yield of UC.

Keywords

upconversion
perovskite
spectroscopy

Supplementary materials

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