Direct Synthesisof Pyrroles by Decarboxylative Ethynyl Methylene Cyclic Carbamates (EMCCs) and Amines Catalyzed by a Binuclear Copper Complexe

23 January 2024, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

An efficient, facile and practical one-pot procedure for the synthesis of polysubstituted pyrroles catalyzed by a binuclear copper complexe using EMCCs as precursors for generating 2-aminoallyl cations was firstly demonstrated. A wide variety of poly-substituted pyrroles were obtained in acceptable to good yields under quite mild conditions.

Supplementary materials

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Title
Direct Synthesisof Pyrroles by Decarboxylative Ethynyl Methylene Cyclic Carbamates (EMCCs) and Amines Catalyzed by a Binuclear Copper Complexe
Description
An efficient, facile and practical one-pot procedure for the synthesis of polysubstituted pyrroles catalyzed by a binuclear copper complexe using EMCCs as precursors for generating 2-aminoallyl cations was firstly demonstrated.
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