Enhanced nonlinear optical properties of Au25 nanocluster oligomers linked by bidentate dithiol

01 December 2023, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Atomically-precise gold nanoclusters covered with thiol ligands are attractive candidates for biophotonics applications. We show that their covalent linking may offer a pathway toward atomically-precise materials with enhanced nonlinear optical properties. Clusters oligomerization leads to moderate modification of the linear optical properties, but has significant impact on their two-photon absorption performance.

Keywords

two-photon absorption
gold nanoclusters
Au25

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