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Leveraging Halogen Interactions for a Supramolecular Nanotube

10 November 2023, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Supramolcular nanotubes in a single crystal were produced from halogenated macrocycles by balancing hydrogen bonds and halogen interactions. A new iodinated macrocycle was prepared, crystallized, and a bonding analysis was performed to evaluate the nature and strength of the involved type I I…I interactions and C=O…I halogen bonds.

Keywords

supramolecular nanotube
halogen bonding
macrocycles
crystallography
bonding analysis

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Version History

Nov 10, 2023 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-dp6kw
D O I: 10.26434/chemrxiv-2023-dp6kw [opens in a new tab]

Funding

European Research Council
949397
Swiss National Science Foundation
PZ00P2_174175
Swiss National Science Foundation
CRSK-2_190366

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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