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Hydrogen-bonded frameworks containing aliphatic 3D linkers show high-capacity water vapour sorption

27 October 2023, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Hydrogen bonded frameworks were prepared from a tetra-amidinium component and three-dimensional cubane and bicyclopentane dicarboxylate linkers. Despite the incorporation of aliphatic components, the frameworks demonstrate strong and reversible uptake of water vapour, with one of the frameworks showing water uptake at very low relative humidity.

Keywords

hydrogen bonded frameworks
HOFs
porous materials
hydrogen bonds
supramolecular chemistry
cubane
bicyclopentane

Supplementary materials

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Now Published

Hydrogen-bonded frameworks containing aliphatic 3D linkers show high-capacity water vapour sorption [opens in a new tab]
Phonlakrit Muang-Non, Carmen Zhou, Lauren K. Macreadie, Nicholas G. White journal article
Chemical Communications
Online publication date: 2024

Version History

Oct 27, 2023 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-j55nv
D O I: 10.26434/chemrxiv-2023-j55nv [opens in a new tab]

Funding

Australian Research Council
DE210101627
Australian Research Council
FT210100495

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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