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Abstract
N-heterocyclic carbenes (NHCs) have been utilized as ligands of metal complexes to catalyze C–C, C–H, C–O, and C–N bond formation reactions. Herein, we present the development of novel supported NHC-Ag(I) complexes as catalysts for Borono-Minisci reactions. Kinetic and cyclic voltammetric studies have evidenced how the structure of both the ligand and complex influence the Ag(I)/Ag(II) redox potential and the reaction efficiency providing a complementary tactic to homo-geneous approaches.
Supplementary materials
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Supporting Information
Description
Experimental procedures, characterization data, HPLC and spectroscopic analysis.
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