Alternative synthetic routes for the encapsulation of proteins: overcoming the elusive mineralization of HKUST-1 in water

31 August 2023, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Alternative synthetic procedures to obtain protein@HKUST-1 composites from protein@Cu-BTC dense composites are reported. pH dependent dense phase precursors are first obtained and their biocompatible transformations into HKUST-1 are characterized. Encapsulation efficiency is affected by the nature of the protein, and can be modulated by the sequential or simultaneous addition of the MOF precursors.

Supplementary materials

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Title
ESI Alternative synthetic routes for the encapsulation of proteins
Description
Contents. Experimental section: Materials and reagents, iIstrumentation and Physico-chemical characterization, Synthesis details. Supplementary Figures and Tables.
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