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Binding Modes of High Stoichiometry Guest Complexes with a Co8L12 Cage Uncovered by Mass Spectrometry

30 August 2023, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We demonstrate how different modes of guest binding to a Co8L12 cubic cage host can be determined using ESI-MS. High stoichiometry guest binding was observed, with binding modes which showed the guests preferentially binding externally, but internal guest inclusion was also seen at higher guest loading.

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Version History

Aug 30, 2023 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-98j7g
D O I: 10.26434/chemrxiv-2023-98j7g [opens in a new tab]

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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