Binding Modes of High Stoichiometry Guest Complexes with a Co8L12 Cage Uncovered by Mass Spectrometry

30 August 2023, Version 1
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We demonstrate how different modes of guest binding to a Co8L12 cubic cage host can be determined using ESI-MS. High stoichiometry guest binding was observed, with binding modes which showed the guests preferentially binding externally, but internal guest inclusion was also seen at higher guest loading.

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