Cambridge Open Engage home
What is Cambridge Open Engage?
How to Submit
Browse
About
News [opens in a new tab]

Ring-opening terpolymerisation of phthalic thioanhydride with carbon dioxide and epoxides

22 June 2023, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

We report the ring-opening terpolymerisation (ROTERP) of phthalic thioanhydride with CO2 and epoxides forming statistical poly(ester-ran-thioester-ran-carbonates) employing heterobimetallic and bicomponent catalysts. Terpolymerisation occurs maintaining polymerisation rates of the faster parent ring-opening copolymerisation and enables the formation of CO2-derived terpolymers with butylene oxide at low CO2 pressure.

Supplementary materials

Title
Description
Actions
Title
ESI
Description
Supplementary Data
Actions

Comments

Comments are not moderated before they are posted, but they can be removed by the site moderators if they are found to be in contravention of our Commenting Policy [opens in a new tab] - please read this policy before you post. Comments should be used for scholarly discussion of the content in question. You can find more information about how to use the commenting feature here [opens in a new tab] .
This site is protected by reCAPTCHA and the Google Privacy Policy [opens in a new tab] and Terms of Service [opens in a new tab] apply.

Version History

Jun 22, 2023 Version 1

Metrics

288
161
0
Views
Downloads
Citations

License

CC logo
CC
BY logo
BY
The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-s2fqd
D O I: 10.26434/chemrxiv-2023-s2fqd [opens in a new tab]

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

Share