Operando wide-field optical microscopy imaging yields a wealth of information about the reactivity of metal interfaces, yet the data are often unstructured and challenging to process. In this study, we harness the power of unsupervised machine learning (ML) algorithms to analyze chemical reactivity images obtained dynamically by reflectivity microscopy in combination with ex situ scanning electron microscopy to identify and cluster the chemical reactivity of particles in Al alloy. The ML analysis uncovers three distinct clusters of reactivity from unlabeled datasets. A detailed examination of representative reactivity patterns confirms the chemical communication of generated OH- fluxes within particles, as supported by statistical analysis of size distribution and finite element modelling (FEM). The ML procedures also reveal statistically significant patterns of reactivity under dynamic conditions, such as pH acidification. The results align well with a numerical model of chemical communication, underscoring the synergy between data-driven ML and physics-driven FEM approaches.
Unsupervised Analysis of Optical Imaging Data for the Discovery of Reactivity Patterns in Metal Alloy
09 June 2023, Version 2
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.