Synthesis and Structural Characterization of Branched Bimetallic AuPd Nanoparticles with highly tunable optical response

Bimetallic nanostructures composed of gold (Au) and palladium (Pd) have garnered increased interest for their application in heterogeneous catalysis. This study reports a simple strategy for manufacturing Au@Pd bimetallic branched nanoparticles (NPs), which offer a tuneable optical response, using polyallylamine-stabilized branched AuNPs as template cores for Pd over-growth. The palladium content can be altered by manipulating the concentration of PdCl42- and ascorbic acid (AA) that are injected, which permit an overgrowth of Pd shell up to ca. 2 nm thick. The homogeneous distribution of Pd at the surfaces of Au NPs can be carried out regardless of their size or branching degree, which allows an adjustment of the plasmon response in the near-infrared (NIR) spectral range. As proof of concept, the nano-enzymatic activity of pure gold and gold-palladium NPs was compared, exploring their Peroxidase-like activity in the oxidation of TMB. The bimetallic AuPd nanoparticles demonstrate an increase in catalytic properties attributed to the presence of palladium at the surface of gold.