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Boronyl borinic esters: preparation as B2pin2/secBuLi/TFAA adducts, structural insights and reactivity in Pd-catalyzed allylic borylation

16 March 2023, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Novel class of diboron reagent boronyl borinic ester was developed that were generated as B2pin2/secBuLi/TFAA adducts. Detailed NMR with solid-state 2D NMR techniques and ESI-MS investigations were used to get structural insights of these new reagent. The new boronyl borinic esters were proved to be promising for allylic borylations of base-sensitive substrates.

Keywords

Diboron reagents
Borylation
Boron ate-complexes
Allyl boronates
Solid-state NMR

Supplementary materials

Title
Description
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Experimental section
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Copies of NMR data and experimental procedures
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Now Published

Boronyl Borinic Esters: Preparation as B2pin2/secBuLi/TFAA Adducts, Structural Insights and Reactivity in Pd‐catalyzed Allylic Borylation [opens in a new tab]
Maxim A. Novikov, Roman A. Novikov, Yury V. Tomilov journal article
Chemistry – An Asian Journal , Volume 18, Issue 12
Online publication date: May 17, 2023

Version History

Mar 16, 2023 Version 2

Version Notes

Description of Solid-state NMR data was clarified.

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2023-gtvm1-v2
D O I: 10.26434/chemrxiv-2023-gtvm1-v2 [opens in a new tab]

Funding

Russian Science Foundation
22-73-10232

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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