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Abstract
Metal bis(terpyidine) complexes comprising directly connected methyldisulfide groups are synthetically accessible and air-stable in solution for ≥7 d, in stark contrast to their thiol analogues. These compounds exhibit a rich solution electrochemistry, and provide a robust foundation for future studies of this prominent class of molecules adsorbed on metal surfaces.
Version notes
The manuscript was revised to focus on the synthetic and solution electrochemical aspects of this work.
Content
Supplementary material
Supporting information for: "Air-stable methyldisulfide-functionalized metal bis(terpyridine) complexes"
Additional experimental details, synthetic, crystallographic, and electrochemical data, 1H and 13C{1H} NMR spectra for all new compounds.
